What is the catalytic reaction of a thermoreactor ?

Chart of heterogeneous general catalysis

A thermoreactor is a gas fueled device that uses a catalytic reaction of fuel, oxygen and heat to generate Infrared.
The catalytic reaction is created by the use of a substance (catalyst) which creates a thermodynamic reaction between the substance and heat. Simply stated, "The changes and increases in the rate of a chemical reaction brought about by a substance (catalyst) that is itself unchanged at the end.
A reaction can happen at different speeds. Explosion is very fast and rust is very slow. A catalytic thermoreactor is somewhere between rust and flame and exhibits heat, yet is absent of a flame.
Ignition starts at approximately 932°F. When a catalyst is added, the reaction happens faster and at a lower temperature. At temperatures of 482°F. Oxidation may take place with all other conditions being equal. Thus, oxidation without ignition and without flame.

 

What is a catalytic thermoreactor?

How the SUNKISS THERMOREACTOR® works

The heat of the unit is the catalytic pad The system is started by the preheating element which is embedded in the cell (pad). At the point of the venturi gas and air which contains the oxygen content, are injected in the cell (pad). When the temperature is correct for oxidation the gas solenoid is opened, permitting gas to flow in the proper proportions. Primary air is used for the main reaction at the venturi. However, secondary air is forced into the face of the cell causing an even reaction (throughout) the cell.
The cell is started by bringing the catalytic pad (cell) to a temperature of 428°F to 572°F, using an armored electrical heating element. The reaction takes place when gas, catalyse, and oxygen are brought together at these temperatures. This takes place at the cell and depending on the gas flow, the reaction goes on and raises temperature to 662°F to 8420°F.
With the addition of forced air, the gas flow can be increased and in such cases temperatures of about 1832°F can be reached. This reveals the main advantages of the catalytic system.
"Although ignition temperature is largely suppressed, no flame appears and the temperature can be regulated by the gas flow over a broad range, which is normally impossible without a catalyst, since beyond 932°F, a flame temperature is immediately reached."

 

Safety aspect :
Enamelling ovens nearly always involve emissions of flammable solvent vapors, which makes safety a prime consideration of such installations.
A major advantage of catalytic radiant panels is that they will not ignite the solvent vapors commonly found in paint and varnish applications.
As a result, in France, radiant panels have been exempted since 1973 from two regulatory requirements based on a 1917 law prohibiting the presence of a flame or hot points above 350°F in workshops, ovens and other enclosed premises containing flammable vapors like those occurring in the treatment of paints and varnishes.
The radiant panel oxidises the solvents (hydrocarbons) coming into contact with its emitting surface by the same token as it oxidises the natural gas fuel of the system.
Thus a solvent concentration gradient is established, having a null value at the panel surface.
Consequently, the solvent concentration throughout the area where the temperature is higher than the self-ignition temperature is less than the lower flammability limit and ignition cannot occur.
With a conventional infrared heater raised to the same temperature on the other hand, ignition will take place if the solvent concentration exceeds the lower flammability limit.

     

Chart of solvent concentration

 

 

Download
Catalysis and SUNKISS thermoreactor (13 pages) - Eric Rogemond - Word 97 (file only available in French)
Infrared’s techniques applied to surface treatment (12 pages) - Eric Rogemond - Word 97 (file only available in French)

 

Try the following links to learn more about our know-how on catalytic technologies ant to see the webpages of our Research and Development department partners:

L.A.C.E. (Laboratory for the Application of the Chemical industry to the Environment), which SUNKISS realise and enhance catalyst's parameters:
http://www.univ-lyon1.fr/ufr_chimie/pages_labos_specifiques/lace/lace.htm

Gaz de France - Research Department, with which SUNKISS has developed a new radiant panel, based energy generation and environment filter
www.gdf.fr

A.F.G. (Association Française du Gaz) of which SUNKISS is a member:
www.afgaz.fr

Literature on catalysis:
http://catalysis.chemweb.com/catalysisonline

I.R.C.(Catalytic Research Institute):
http://catalyse.univ-lyon1.fr

General bibliography:
www.chemweb.com

Claude Bernard Lyon 1 University:
www.univ-lyon1.fr

 

 
© 2001, SUNKISS – All rights reserved.
Sunkiss, its logo and Thermoreactor are registered trademarks of Sunkiss.